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![]() ![]() The movie got two Direct to Video sequels, though they share none of the creative cast and don't follow any of the characters introduced in the first film (except in the second sequel, which is about the origins of the vampire Santanico Pandemonium), with the only connecting thread being the vampire bar/lair, The Titty Twister: Of course, this has become widely spoiled and, as such, can lose most of its effect (in fact, many people probably rented the film and wondered where the hell the vampires were for the first half). ![]() What happens at this point is a very sudden and unexpected Genre Shift when it turns out that the bar is a front for a clan of vampires, and the brothers have to fight for their survival through the night (hence the title). They go to a trucker bar, the Titty Twister, to spend the night as they wait for their rendezvous. Causing death and destruction wherever they go, they eventually manage to sneak past the border with Mexico by taking a pastor and his two teenage children hostage in their RV. The plot centers around the Gecko brothers, Seth (Clooney) and Richie (Tarantino), two dyed-in-the-wool criminals on the run from the police after a prison break in Texas. Aside from that unfortunate business, everything's hunky-dory.įrom Dusk Till Dawn is a 1996 action horror film written by Quentin Tarantino, directed by Robert Rodriguez, and starring Tarantino, George Clooney, Harvey Keitel, and Juliette Lewis. ![]() The world's my oyster, except for the fact that I just rammed a wooden stake in my brother's heart because he turned into a vampire, even though I don't believe in vampires. ![]() ![]() Studies of the impact of the MELD on liver allocation and outcomes of liver transplantation included in the integrative review Eight answered the guiding question and were included in the final sample of the present review: four were from Pubmed, two from Lilacs and two from SciELO ( Figure 1). Using this tool, the 12 articles were selected and read in full. Articles with a score of six to ten were classified as being of good methodological quality and low bias (level A) 21 and were kept in the sample. These remaining selected articles were evaluated using a methodologically rigorous tool adapted from the Critical Appraisal Skills Programme (CAPS) 21 containing questions on the clarity of the objective, the adequacy of the methodology, theoretical and methodological procedures, sample selection, the relation between researcher and subject, ethical considerations, rigor and the foundation of data analysis, declaration of results, and the importance of the research.Įach item was worth one point and the score was the sum of points. Seven of the remaining articles were excluded for being duplicates, leaving 12 articles for analysis. A reading of available titles and abstracts led to the exclusion of 57 articles, 40 from Pubmed, eight from Lilacs and nine from SciELO. The initial search found 76 articles, 49 on Pubmed, 13 on Lilacs and 14 on SciELO. The selection criteria for articles stipulated that they be available in full, in English, Spanish or Portuguese and published between 20. ![]() The articles were searched for using headings controlled by the Virtual Health Library by way of the Health Sciences Headings "liver transplant," "survival analysis" and "end-stage liver disease", and the MESHs (Medical Subject Headings) "liver transplantation," "survival analysis" and "end-stage liver disease". The present study thus aims to examine the information produced on the MELD and its relation to survival and is guided by the following question: What impact does the MELD have on liver allocation and the results of liver transplants?Ī bibliographical survey was carried out in October 2015 using three indexed databases: Literatura Latino-Americana em Ciências da Saúde (Lilacs), the Scientific Eletronic Library Online (SciELO) and Pubmed. This change brought about a reduction of 3,5% in waiting list mortality, an increase of 10.2% in deceased donor transplants and a drop of 12% in patients scheduled for transplant 3,15.Įxamination of post-transplant survival showed that there may be a relation not defined by a high MELD score alone, but associated with the scarcity of organs, which led to the expansion of criteria for deceased donors beyond comorbidities. Since then, a policy has been adopted of using this procedure in more seriously ill patients, with the exception of emergencies and prioritized liver transplants, where allocation is conducted using other criteria, in accordance with current legislation 1, 4, 15, 27. The MELD as indicator of the severity of the clinical status of the recipient was introduced as a criterion in Brazil in 2006 by Decree 1160. It is thus possible to obtain a good predictor of mortality, with a score close to 40 indicating minimal likelihood of survival within three months 1, 5, 8. In 2002, the United States started using this score as a criterion for liver allocation 13, 26.Ī logarithmic calculation involving serum creatinine, bilirubin and International Normalized Ratio is used to obtain the MELD score for recipients aged over 12 years. However, it was noted that mortality on the waiting list was not related only to the waiting time 3, 10.ĭescribed for the first time in 2000, the aim of the MELD (Model for End-stage Liver Disease) score was to predict the three-month survival rate in patients who underwent a transjugular intrahepatic portosystemic anastomosis 1, 3, 8.Ī 2001, study validated the MELD score as a measure of the probability of mortality within three months in transplant patients with end-stage chronic liver disease. At this time, the criterion used for conducting a transplant was time. In 1997, the National Organ Transplant and Notification and Distribution Centers System was set up, which enabled the introduction of a Single Technical Register and a single waiting list 1. The organ and tissue allocation system in Brazil has been through various phases that have led to better organization and greater credibility, reducing waiting lists and hence mortality 1. Since the first transplant, in 1963, many changes have significantly improved its success rate 18. ![]() The aim of a liver transplant is to increase the survival of a patient with end-stage liver disease and to improve quality of life 15. ![]() ![]() ![]() ✓ Backup and restore contacts from saved business cards. ✓ Search in Maps for the address of your biz contact with just one tap from ABBYY Business Card Reader ✓ Find out more about your new biz contacts on the most popular social networks – Linkedln, Facebook and Twitter right from your BCR! ✓ Cross-platform sharing of business cards across Android and iOS for all businessman using ABBYY Business Card Reader (thanks to AllJoyn™ by Qualcomm Innovation Center Inc.). ✓ Forward recognized contact data from Card Holder via e-mail as VCard and JPEG file or via SMS as a plain text. 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ABBYY Business Card Reader BETA scans and manages your business cards and contacts in a flash. ![]() ![]() ![]() Discounts and any amounts from limited time promotions that apply to your order, if any, and which are still in effect, will be automatically deducted from your order. The Service is only available to customers with shipping addresses in the 50 United States and the District of Columbia.ĭiscounts and any limited time promotions associated with the Service apply only to Eligible Products displaying the offer message on the product detail page on the Canon Direct website (). Your participation in the Service is personal to you, and you may not assign or transfer your enrollment, or any of the benefits of the Service, to any third party without our authorization. The eligible products that may be ordered through the Service (the identity of which are subject to change) are set forth on the product detail page on the Canon Direct website () with the option to select the Service displayed (each, an "Eligible Product"). If we do so, you will only be charged for orders that have been shipped to you. We may, in our sole discretion, terminate your enrollment at any time without notice. When you are enrolled, the Service will automatically create a new order for Eligible Products according to the shipment schedule applicable to the frequency of the Service you have selected, until you cancel. All such changes will apply to future orders. We reserve the right to change the Service benefits, including discount amounts and eligibility used to determine discount amounts, at any time in our sole discretion. By placing an order through, or otherwise using, the Service, you accept, and agree to be bound by, these terms, conditions, limitations and requirements. Please note that your use of the Service is also governed by Canon Direct’s Terms of Use and our Privacy Statement, each of which (as changed over time) are incorporated into these Terms, and all of which govern our respective rights and obligations concerning the Service. ("Canon USA," "we" or "us") and govern your and our respective rights and obligations relating to the Service. These Terms are between you and Canon U.S.A., Inc. Auto Replenishment System (the "Service"). Canon LP-E6N Lithium-Ion Battery Pack (7.The following are the terms and conditions ("Terms") for the Canon U.S.A., Inc.Canon EOS 6D Mark II DSLR Camera (Body Only).Built-In GPS, Bluetooth & Wi-Fi with NFC.6.5 fps Shooting Time-Lapse & HDR Movie.Native ISO 40000, Expanded to ISO 102400.3" 1.04m-Dot Vari-Angle Touchscreen LCD.Users will have access to many connectivity options as well, such as Wi-Fi, NFC, and Bluetooth, for connecting to a smart device, and built-in GPS for geotagging your photos. Additionally, the body design has received an upgrade with improved ergonomics and durability, including dust and water resistance. Users will also have the ability to create 4K time-lapse movies as well as HDR video with dedicated settings and modes. 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Their members, “help others achieve their full potential by improving their knowledge, skills, and abilities in the workplace.” Their toolkit is a collection of job aids, guides, templates, and resources designed to help their chapter leaders solve their own problems. Furthermore, they are on a mission to create a world that works better. If you’ve never heard of the ATD, they are a global organization dedicated to what I call the KSB (Knowledge, Skills, Behaviors). The ATD (Association for Talent Development), offers a CLC learning toolkit for their chapter leader community. And solving your own problems should be the goal of a well-designed learning toolkit. These toolkits inside their Creator Academy are expertly crafted resources to help the user solve their own problems. For instance, they come with courses, useful downloads, exemplars, virtual training, and perks. YouTube has Learning Toolkits designed to help content creators optimize their channels and their businesses. In other words, toolkits can help translate theory into practice, and typically target one issue or one audience.” Let’s begin with the toolkit.Īccording to the American Library Association, “A toolkit is a collection of authoritative and adaptable resources for front-line staff that enables them to learn about an issue and identify approaches for addressing them. ![]() It’s not that complex if you break it down, list it out, and then assemble the brains to make it work. As a result, a dynamic playbook, toolkit, and calendar is the answer. Your learning culture depends upon everyone knowing why they are learning something. My point is this: everyone involved in making training or learning needs to be on the same page. More commonly, they responded like this: “We need this program updated because it’s out of date” or “We need new product training”. How does this course fit into the curriculum? Some knew the answer right away. 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Researchers and entrepreneurs working at the frontier of ocean CDR must swim against a rip current of quandaries, from regulatory and technical obstacles to equity concerns. Just measuring the efficacy and durability of carbon removal remains a huge challenge, considering oceans cover ~70% of the planet with constantly shifting currents. At such a large scale and open system, it’s difficult to anticipate the ripple effects caused by adjusting the chemistry or biology of marine ecosystems for accelerated carbon sequestration purposes. Venture-backed companies like Running Tide, Ebb Carbon, and Brilliant Planet are already working on solutions that would accelerate the ocean’s absorption of CO2, but the science is far from settled. Nevertheless, we’ve created such a mess on Aisle Earth that it’s now necessary to mop vigorously with all possible carbon sponges. The field of ocean-based carbon dioxide removal (CDR) is nascent, complicated, and risky-even compared with complex terrestrial carbon removal tech. Putting our terrestrial bias aside, the ocean is the world’s largest carbon sink-on the order of ~50x more carbon than is currently in the atmosphere.īut it’s no small feat to wring out nature’s sequestration sponge. Documenting the successful use of this technology could help bring “low-tech”, low-cost, CO2 to algae, carbon capture to multiple size industries and could accelerate the use of “low-tech” carbon capture.Us land-dwellers waste a lot of breath on atmospheric carbon capture. An understanding of process requirements to apply this technology to existing industries would go far in advancing carbon capture opportunities. Data and process information are being collected and developed to facilitate feasibility and modeling evaluations of the CO2 to algae technology. Three electric power generation plants (coal and fuel oil fired) equipped to send flue-gas emissions to algae culture at demonstration facilities are being studied. Information is being generated for modeling analyses and examination of the breakthrough potential of transformational technologies and their associated environmental implications using an economic evaluation model. The operations are being studied for the use of CO2 from flue gas for algae growth along with the production of biofuels and other useful products to prepare a comprehensive characterization of the economic feasibility of using algae to capture CO2. A study of operational demonstration projects is being undertaken to evaluate the benefits of using algae to reduce CO2 emissions from industrial and small-scale utility power boilers. 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PPSSPP or ROM game files are usually available in Zip, RAR, 7z format, which can then be extracted after downloading one of them. Top 100 PPSSPP Games Currently to Download If you have this emulator installed, you don’t need to be looking for which one to play on your device, since in this list we share the best ones. Download in this article the 100 best PSP or PPSSPP games for the Android PSP emulator. ![]() ![]() This analysis suggests also that the naked cation Co 3+ would oxidize chloride to chlorine, precluding the formation of CoCl 3. An authoritative monograph states, "Apart from CoF 3, the only known halides of cobalt are the dihalides." The reduction potential for Co 3+ + e - → Co 2+ is more favorable (+1.92 V) than the reduction Cl 2 to Cl - (+1.36 V). ![]() The existence of cobalt(III) chloride, CoCl 3, is disputed, although it is listed in some compendia. The German chemist Alfred Werner was awarded the Nobel prize in 1913 for his studies on a series of these cobalt(III) compounds, work that led to an understanding of the structures of such coordination compounds. Unlike Co(II) complexes, Co(III) complexes are very slow to exchange ligands, so they are said to be kinetically inert. Other highly basic ligands including carbonate, acetylacetonate, and oxalate induce the formation of Co(III) derivatives. The reaction is often performed in the presence of charcoal as a catalyst, or hydrogen peroxide is employed in place of air. For example:Ĥ CoCl 2♶H 2O + 4 Cl + 20 NH 3 + O 2 → 4 Cl 3 + 26 H 2O In the presence of ammonia or amines, cobalt(II) is readily oxidised by atmospheric oxygen to give a variety of cobalt(III) complexes. This 19-electron species is a good reducing agent, being readily oxidised to the yellow 18-electron cobaltacenium cation, which is isoelectronic with ferrocene. ![]() Reaction of anhydrous CoCl 2 with sodium cyclopentadienylide in THF gives the black sandwich compound cobaltocene. For example, the reaction of 1-norbonyllithium with CoCl 2 produces the brown, thermally stable cobalt(IV) tetralkyl - the only compound of its kind for which the detailed structure is fully known : ![]() In the laboratory, cobalt(II) chloride serves as a standard precursor for the synthesis of other cobalt compounds. Otherwise, aqueous solutions of cobalt(II) chlorides behave like other cobalt(II) salts, such as precipitating CoS upon treatment with H 2S. These cobalt (II) complexes are usually either octahedral or tetrahedral. Similarly, paper impregnated with cobalt chloride, known as "cobalt chloride paper" is used to detect the presence of water.ĬoCl 2♶H 2O and CoCl 2 are weak Lewis acids that convert to many other complexes. When cobalt(II) chloride is added as an indicator, the drying agent is blue when still active, pink when exhausted, corresponding to anhydrous and hydrated CoCl 2, respectively. In the US calcium sulfate is sold as a drying agent under the trade name Drierite. The hydrated form can be prepared from cobalt(II) hydroxide or cobalt(II) carbonate and hydrochloric acid.Ī common use for cobalt(II) chloride was for the detection of moisture, for example in drying agents such as silica gel this use was disscontinued due to the carcenogenic nature of cobalt salts. CoCl 2♶H 2O is deliquescent and the anhydrous salt CoCl 2 is hygroscopic, readily converting to the hydrate.Ĭobalt(II) chloride can be prepared in its anhydrous form from cobalt metal and chlorine gas: ![]() It has the interesting property that a concentrated aqueous solution is red at room temperature, but becomes blue when heated. This species dissolves readily in water and alcohol. In the solid state CoCl 2♶H 2O contains trans-♲H 2O, two water molecules in its formula unit being water of crystallization. The rose hexahydrate is one the most common cobalt compounds in the laboratory.Īqueous solutions of both CoCl 2 and the hydrate contain the species 2+. Because of this dramatic color change and the ease of the hydration/dehydration reaction, "cobalt chloride" is used as an indicator for water. CoCl 2 is blue, and CoCl 2♶H 2O is deep rose. Rhodium(III) chloride Iridium(III) chlorideĮxcept where noted otherwise, data are given for materials in their standard state (at 25 ☌, 100 kPa) Infobox disclaimer and referencesĬobalt(II) chloride is the chemical compound with the formula Co Cl 2, although the term is used also to refer to the hexahydrate, which is a different chemical compound. 2 Dangerous for the environment ( N)Ĭobalt(II) fluoride Cobalt(II) bromide Cobalt(II) iodide Cobalt(II) oxide ![]() |
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